# Crystal structure of 4-fluoro-N-[2-(4-fluorobenzoyl)hydrazine-1-carbonothioyl] benzamide
> Firdausiah S.

URL kanonis: https://discover.unhas.ac.id/publications/crystal-structure-of-4-fluoro-n-2-4-fluorobenzoylhydrazine-1-carbonothioyl-benza
Jurnal / Konferensi: Acta Crystallographica Section E Structure Reports Online
Tahun terbit: 2014
DOI: https://doi.org/10.1107/S1600536814015761
ISSN: 16005368
Citations: 4

## Authors
- Firdausiah S.

## Abstract
In the title compound, C15H11F2N3O2S, the dihedral angle between the fluoro-benzene rings is 88.43 (10)° and that between the central semithiocarbazide grouping is 47.00 (11)°. The dihedral angle between the amide group and attached fluoro-benzene ring is 50.52 (11)°; the equivalent angle between the carbonyl-thio-amide group and its attached ring is 12.98 (10)°. The major twists in the mol-ecule occur about the C-N-N-C bonds [torsion angle = -138.7 (2)°] and the Car-Car-C-N (ar = aromatic) bonds [-132.0 (2)°]. An intra-molecular N-H⋯O hydrogen bond occurs, which generates an S(6) ring. In the crystal, the mol-ecules are linked by N-H⋯O and N-H⋯S hydrogen bonds, generating (001) sheets. Weak C-H⋯O and C-H⋯F inter-actions are also observed.

## Keywords
- Dihedral angle
- Hydrogen bond
- Fluorobenzene
- Chemistry
- Intramolecular force
- Ring (chemistry)
- Crystallography
- Molecule
- Crystal structure
- Benzamide
- Crystal (programming language)
- Amide
- Stereochemistry
- Organic chemistry
- Computer science
- Programming language
- Benzene

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Sumber: Discover Unhas — RIMS Universitas Hasanuddin.
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